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Vol 9, Issue 1, 2019
Pages: 302 - 310
Original scientific paper
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Received: >> Accepted: >> Published: 09.10.2019. Original scientific paper

METHODS FOR THE EPOXIDATION OF VEGETABLE OILS AND THEIR DERIVATIVES

By
Olga Govedarica ,
Olga Govedarica

Faculty of Technology Novi Sad, University of Novi Sad , Novi Sad , Serbia

Milovan Janković ,
Milovan Janković

Faculty of Technology Novi Sad, University of Novi Sad , Novi Sad , Serbia

Snežana Sinadinović-Fišer ,
Snežana Sinadinović-Fišer

Faculty of Technology Novi Sad, University of Novi Sad , Novi Sad , Serbia

Vesna Teofilović ,
Vesna Teofilović

Faculty of Technology Novi Sad, University of Novi Sad , Novi Sad , Serbia

Mirjana Jovičić ,
Mirjana Jovičić

Faculty of Technology Novi Sad, University of Novi Sad , Novi Sad , Serbia

Ayse Zehra Aroguz
Ayse Zehra Aroguz

Chemistry Department, Engineering Faculty, Istanbul University-Cerrahpaşa , Istanbul , Turkey

Abstract

 Epoxidized vegetable oils have seen increasing application diversity in chemical and polymer industry. They are mainly used as stabilizer and plasticizer for polyvinyl chloride (PVC). However, they are also promising intermediates for the production of other vegetable oil derivatives. Vegetable oils are epoxidized in the industry with in situ formed organic peracid, commonly performic or peracetic acid. The shortcomings of this method include the occurrence of side reactions as well as the necessity for treatment of waste streams. Therefore, other epoxidation methods such as epoxidation with organic and inorganic hydroperoxides and epoxidation with dioxiranes have been studied extensively. Also, enzymatic epoxidation has attracted much attention in recent years. The advantages and shortcomings of the studied epoxidation methods will be discussed in the present work. 

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